Tribology & Lubrication

Bhavik Kasundra · March 15, 2024

Interfacing surfaces in relative motions, including friction, wear and erosion

Lubrication Engineer

Friction

Resisting force between surfaces with relative movement

  • Energy loss
  • Increased power consumption
  • Temperature Increase
  • Noise increase
  • Wear of component with dimensional change

Types

  • Static
  • Kinetic
  • Rolling

Wear

Material loss out of body as consequence of tribological stress

  • Abrasive wear: Surface peaks of harder body making scratches in softer body
    • 2 body abrasion: Micro cutting of body with hard roughness peaks of opposing body
    • 3 Body Abrasion: Micro cutting of both bodies with hard particles within intermediate layer
    • Abrasive wear Leads to material losses in form of troughs which affects Lubrication film & Contaminates the lube oil.
  • Adhesive wear ?
    • Results in Seizure
    • Caused by Poor lubrication or Insufficient oil film
    • Characterized by local micro-welding points between peaks of both surfaces, with damage following separation.

Wear & Wear Mechanisms

  • Corrosive: Chemical reaction with surrounding environment.
  • Pitting: Surface cavitation caused by rolling contact
  • Cavitation: Formation and collapse of bubbles on surface due to rapid pressure changes

Function of Lubricant

  • Friction Control → Separates moving surfaces
  • Wear Control → Reduces abrasive wear
  • Corrosion Control → Protects Surfaces from Corrosive substances
  • Temperature Control → Absorbs and Transfer Heat
  • Contamination Control → Transports Particles and other contaminants of Filters\Separators
  • Power Tran-mission → Transmits force and Motion

Lubrication Regimes

  • Hydrodynamic: Full film lubrication or Surface Separation
    • Pressure generated by Sliding velocity of layers
    • Adequate oil supply
    • Oil Viscosity
    • Found in Journal Bearings.
  • Thin Film or Mixed
    • Film thickness ~ Surface Asperities
  • Elasto-Hydrodynamic
    • Found in Gears, anti-friction bearings, cams
    • Elastic Deformation of surfaces
    • Large increase in Pressure viscosity
  • Boundary
    • Film thickness < Surface Asperities

Lubrication in Bearings Stages

Startup (No oil Pressure), Boundary Lubrication

Intermediate: Low Oil pressure (Mixed Lubrication)

Running: Full oil pressure (Hydrodynamic Lubrication)

Structure of Lubricating oil

Base stock (Mineral\Synthetic\Vegetable) Provides

  • Viscosity for controlling friction and wear
  • Corrosion and Oxidation resistance
  • Heat transfer
  • Contamination suspension
  • Additive suspension

Additives (Organic & Inorganic)

  • Enhances existing Base stock properties
  • Surpasses undesirable base stock props
  • New properties

Base Oil Technologies

Mineral oils and Hydrocarbons

  • Paraffins
  • Branched paraffins
  • Naphthene
  • Aromatics

Chain Length : C25- C40

Refining Process

  • Solvent Refining
  • Hydro Cracking

API Base stock Categories

Viscosity index increases as group increases

  • Group 1 - Solvent Refined Mineral oils
  • Group 2 - Hydro Processed mineral oil
  • Group 2+ - Hydro Cracked mineral oils
  • Group 3 - Severe Hydrocracked Synthetic oils
  • Group 4 - Poly-alpha olefins (PAO’s)
  • Group 5 - Other Synthetics

Properties to keep in mind

  • Viscosity
  • Moisture
  • TBN Total Base num : Measure of ability to neutralize acid
  • TAN Total Acid Number: measure of acidity
  • Flash point, Pour point (lowest point at which oil is observed to flow)
  • Thermal operating range
  • Fire resistance
  • Oxidation stability
  • Lubricity
  • Shear stability
  • Detergency
  • Seal compatibility
  • Contaminant sensitivity
  • INFRA Red analysis (Water, Oxidation, Nitration)
  • Foam test
  • Particle Counting
  • Water Metals

Components of Grease

  • Base Oil \ Mineral Oil \ Synthetic Oil
  • Thickeners \ Soaps
  • Additives \ Solid Lubricants \ Corrosion Inhibitors \ Adhesion Improvers

Properties

Role of Additives

  • Extreme Pressure
    • Mitigate effects of high load boundary lubrication
    • Reacts with surface under heat to form ductile films
    • Sulphur-phosphorous compounds, graphite, Borate or MoS2
  • Anti Wear
    • Reduce wear and friction from sliding contact
    • Surface active materials form low shear strength between sliding surfaces
    • ZDDP, TCP
  • Corrosion Inhibitors
    • Reduce rust formation on iron surface
    • Additive is metal -phillic and hydrophobic
    • Long chain fatty acids, Naphthalene sulphorates, Phosphoric acid derivatives
  • Anti-Oxidants or Oxidation Inhibitors
    • Inhibit reaction with oxygen
    • Additive oxidizes in preference to oil seeking out free radicals and peroxides
    • Hindered Phenols, Zinc di thiophosphates, Aromatic amines
  • Foam Inhibitors
    • Prevents formation of foam and aerated oils
    • Weakness bubbles allows them to break rapidly
    • Organic polymers, Methyl silicone
  • Viscosity Index Improvers
    • Additive expands at higher temperature, slowing down thinning rate of oil
    • Ethylene propylene copolymers, polymethacrylates
  • Dispersants
  • Detergents

Lube Oil Properties

  • Viscosity grading (ISO VG) → cSt vs Temp
  • Kinematic Viscosity
  • Dynamic or Absolute Viscosity = KV * Density

Viscosity Index

  • Mineral oils ≥ 80
  • Hydrotreated or Hydrocracked ≥ 95
  • Poly-alpha-olefins ≥ 120
  • Silicones ≥ 300

Oxidation of Oils

Catalysts of oxidation

  • Increased Viscosity, acids, oil darkening

Free radical mechanism via alkyl peroxy radicals

Performance Testing of Oils (ASTM)

  • Rotating pressure vessel oxidation (RBOT)
  • Grease oxidation stability
  • Turbine oil oxidation test TOST
  • Rust Test
  • Copper Strip Corrosion Test
  • Grease Rolling Bearing Rust Test
  • Demusibility

Testing

  • Viscosity
    • Decrease
      • Thermal Cracking
      • Shearing
      • Mixture with lower viscosity oil, Solvents
    • Increase
      • Mix with high viscosity oil
      • Oxidation, Nitration
  • Water Contamination
    • Crackle test
    • Karl Fisher Test
    • TAN
    • TBN

Oil analysis

  • Spectrography
  • Ferrography

Desiccant Breather

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